Don't make any plans because these shows might consume your life. Good animes tend to do that.
1. Attack on Titan
Recommended if you like:
Game of Thrones, The Walking Dead, very sad things constantly happening
2. Big O
Recommended if you like:
Batman: The Animated Series, Dark City, big robots
3. Death Note
Recommended if you like:
Hannibal, The Following, Orphan Black
4. Fullmetal Alchemist Brotherhood
Recommended if you like:
Inglorious Basterds, Indiana Jones, Harry Potter
5. Tengen Toppa Gurren Lagann
Recommended if you like:
Independence Day, Big Fish, The Wonder Years
6. Puella Magi Madoka Magica
Recommended if you like:
Buffy The Vampire Slayer, Teen Wolf, The Vampire Diaries
7. Neon Genesis Evangelion
Recommended if you like:
Pacific Rim, serious teenage angst, having your brain melted out of your ears
8. Rurouni Kenshin
Recommended if you like:
When Harry Met Sally, sprawling samurai stories, lots of action